Isotopic compositions
| Manufacturer Family | Applied/standard | Isomer ? | Isomer enriched | Number of batch | Commercial Name/Formulation | Purity (%) | δ13C (‰) | ± (‰) | δ37Cl (‰) | ± (‰) | δ15N (‰) | ± (‰) | δ2H (‰) | ± (‰) | Measurement method | Reference: DOI Number | Reference Citation |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Chemos | Standard | Bulk | No | ? | -28.6 | 0.1 | -4.3 | 0.2 | EA-IRMS + GC−qMS | 10.1021/acs.est.1c03981 | C. Torrento, V. Ponsin, C. Lihl, T. B. Hofstetter, N. Baran, M. Elsner and D. Hunkeler, 2021.Triple-Element Compound-Specific Stable Isotope Analysis (3D-CSIA): Added Value of Cl Isotope Ratios to Assess Herbicide Degradation.Environmental Science & Technology, 55, 13891-13901. | ||||||
| Home-made | Standard | Bulk | No | artificial standard | na | -22.5 | 0.3 | 5.1 | 0.3 | EA-IRMS + GC−qMS | 10.1021/acs.est.1c03981 | C. Torrento, V. Ponsin, C. Lihl, T. B. Hofstetter, N. Baran, M. Elsner and D. Hunkeler, 2021.Triple-Element Compound-Specific Stable Isotope Analysis (3D-CSIA): Added Value of Cl Isotope Ratios to Assess Herbicide Degradation.Environmental Science & Technology, 55, 13891-13901. | |||||
| Oskar Tropitzsch | Standard | Bulk | No | na | -30.4 | 0.1 | 0 | 0.1 | 0.3 | 0.1 | EA-IRMS + GC−qMS | 10.1021/acs.est.1c03981 | C. Torrento, V. Ponsin, C. Lihl, T. B. Hofstetter, N. Baran, M. Elsner and D. Hunkeler, 2021.Triple-Element Compound-Specific Stable Isotope Analysis (3D-CSIA): Added Value of Cl Isotope Ratios to Assess Herbicide Degradation.Environmental Science & Technology, 55, 13891-13901. | ||||
| Chemos | Standard | Bulk | No | 96.2 | -28 | 0.2 | -2.8 | 0.1 | GC−qMS | 10.1021/acs.analchem.9b02497 | Ponsin, V., et al., Compound-Specific Chlorine Isotope Analysis of the Herbicides Atrazine, Acetochlor, and Metolachlor. Anal. Chem., 2019. 91(22): p. 14290-14298. | ||||||
| Chemos | Standard | Bulk | No | 96.2 | -28 | 0.1 | 0.7 | 0.2 | EA-IRMS | 10.1039/c9an00160c | Torrento C., et al, Solid-phase extraction method for stable isotope analysis of pesticides from large volume environmental water samples, Analyst, 2019, 144, 2898 | ||||||
| Chemos | Standard | Bulk | No | 96.2 | -28.2 | 0.4 | 1.3 | 0.3 | GC-IRMS | 10.1039/c9an00160c | Torrento C., et al, Solid-phase extraction method for stable isotope analysis of pesticides from large volume environmental water samples, Analyst, 2019, 144, 2898 | ||||||
| Sigma Aldrich | Standard | Bulk | No | 97.2 | -30.2 | 0.06 | EA–IRMS | 10.1016/j.chemosphere.2013.10.027 | Elsayed, OF, et al, Using compound-specific isotope analysis to assess the degradation of chloroacetanilide herbicides in lab-scale wetlands, Chemosphere 99 (2014) 89–95 | ||||||||
| Sigma Aldrich | Standard | Bulk | No | 97.2 | -31 | 0.22 | GC–C–IRMS | 10.1016/j.chemosphere.2013.10.027 | Elsayed, OF, et al, Using compound-specific isotope analysis to assess the degradation of chloroacetanilide herbicides in lab-scale wetlands, Chemosphere 99 (2014) 89–95 | ||||||||
| Sigma Aldrich | Standard | Bulk | No | 97.2 | -30.7 | 0.26 | GC–C–IRMS extracted | 10.1016/j.chemosphere.2013.10.027 | Elsayed, OF, et al, Using compound-specific isotope analysis to assess the degradation of chloroacetanilide herbicides in lab-scale wetlands, Chemosphere 99 (2014) 89–95 | ||||||||
| SYNGENTA | Applied | S | Yes | Mercanto Gold / Dual Gold | -32.2 | 0.5 | 1.9 | 0.5 | GC-C-IRMS | 10.1016/j.watres.2018.03.061 | Alvarez-Zaldivar P., et al, Pesticide degradation and export losses at the catchment scale: Insights from compound-specific isotope analysis (CSIA), WaterResearch, 139(2018)198e207 | ||||||
| Unknown | Standard | S | Yes | -4.28 | 0.17 | GC-MC-ICPMS | 10.1021/acs.analchem.9b02463 | Lihl, C., et al, Toward Improved Accuracy in Chlorine Isotope Analysis: Synthesis Routes for In-House Standards and Characterization via Complementary Mass Spectrometry Methods, Anal. Chem. 2019, 91, 12290−12297 | |||||||||
| SYNGENTA | Applied | S | Yes | PE-1521CHE9B00051 | Mercantor Gold / Dual Gold / Camix | -31.9 | 0.31 | GC-C-IRMS | 10.5194/hess-21-5243-2017 | Lutz, RS., et al, Pesticide fate on catchment scale: conceptual modelling of stream CSIA data, Hydrol. Earth Syst. Sci., 21, 5243–5261, 2017 | |||||||
| Sigma Aldrich | Standard | S | Yes | SZBB315XV | -31.2 | 0.5 | 0.4 | 0.7 | GC-C-IRMS | 10.1016/j.chemosphere.2018.09.056 | Masbou, J., et al, Carbon and nitrogen stable isotope fractionation during abiotic hydrolysis of pesticides, Chemosphere 213 (2018) 368e376 | ||||||
| Sigma Aldrich | Standard | S | Yes | -30.2 | 0.2 | EA–IRMS | 10.1016/j.agee.2020.107257 | Perez-Rodríguez, P., A. D. Schmidt, S. Gangloff, J. Masbou and G. Imfeld, 2020.Plants affect the dissipation and leaching of anilide pesticides in soil mesocosms: Insights from compound-specific isotope analysis (CSIA).Agriculture, Ecosystems and Environment, 308, 107257. | |||||||||
| Sigma Aldrich | Standard | S | Yes | 97 | -30.6 | 0.6 | GC–C–IRMS | 10.1016/j.agee.2020.107257 | Perez-Rodríguez, P., A. D. Schmidt, S. Gangloff, J. Masbou and G. Imfeld, 2020.Plants affect the dissipation and leaching of anilide pesticides in soil mesocosms: Insights from compound-specific isotope analysis (CSIA).Agriculture, Ecosystems and Environment, 308, 107257. | ||||||||
| Toronto Research | Standard | S | Yes | -28.9 | 0.16 | -0.06 | 0.26 | 10.1016/j.chemosphere.2024.141488 | Masbou, J., Höhener, P., Payraudeau, S., Martin-Laurent, F., & Imfeld, G. (2024). Stable isotope composition of pesticides in commercial formulations: The ISOTOPEST database. Chemosphere, 141488. | ||||||||
| SYNGENTA | Applied | S | Yes | PE-1415SAV8K18014 | Dual Gold SAFENEUR | 91 | -31.93 | 0.2 | 2.22 | 0.44 | GC-IRMS | 10.1016/j.chemosphere.2024.141489 | Masbou, J., Höhener, P., Payraudeau, S., Martin-Laurent, F., & Imfeld, G. (2024). Stable isotope composition of pesticides in commercial formulations: The ISOTOPEST database. Chemosphere, 141488. | ||||
| SYNGENTA | Applied | S | Yes | PE-1347SAV7K17020 | CAMIX 440 | 40 | -31.69 | 0.15 | 2.64 | 0.26 | GC-IRMS | 10.1016/j.chemosphere.2024.141490 | Masbou, J., Höhener, P., Payraudeau, S., Martin-Laurent, F., & Imfeld, G. (2024). Stable isotope composition of pesticides in commercial formulations: The ISOTOPEST database. Chemosphere, 141488. | ||||
| SYNGENTA | Applied | S | Yes | PE-1521CHE9B00051 | MERCANTOR GOLD | 96 | -32.6 | 0.5 | GC-IRMS | 10.1016/j.chemosphere.2024.141491 | Masbou, J., Höhener, P., Payraudeau, S., Martin-Laurent, F., & Imfeld, G. (2024). Stable isotope composition of pesticides in commercial formulations: The ISOTOPEST database. Chemosphere, 141488. | ||||||
| SYNGENTA | Applied | S | Yes | PE-1521CHE9B00051 | MERCANTOR GOLD | 96 | -31.34 | 0.15 | GC-IRMS | 10.1016/j.chemosphere.2024.141492 | Masbou, J., Höhener, P., Payraudeau, S., Martin-Laurent, F., & Imfeld, G. (2024). Stable isotope composition of pesticides in commercial formulations: The ISOTOPEST database. Chemosphere, 141488. | ||||||
| PHYTEUROP | Applied | S | Yes | S-Metolastar | 96 | -32.15 | 0.16 | 2.19 | 0.1 | GC-IRMS | 10.1016/j.chemosphere.2024.141493 | Masbou, J., Höhener, P., Payraudeau, S., Martin-Laurent, F., & Imfeld, G. (2024). Stable isotope composition of pesticides in commercial formulations: The ISOTOPEST database. Chemosphere, 141488. | |||||