Isotopic compositions
| Manufacturer | Applied/standard | Isomer ? | Isomer enriched | Batch/Lot n° | Commercial Name/Formulation | Purity (%) | δ13C (‰) | ± (‰) | δ37Cl (‰) | ± (‰) | δ15N (‰) | ± (‰) | δ2H (‰) | ± (‰) | Measurement method | Reference: DOI Number | Reference Citation |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| BAYER | Applied | Bulk | No | 99 | -29.8 | 0.2 | -0.1 | 0.1 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| BAYER | Applied | Bulk | No | 99 | -26.3 | 0.2 | -0.4 | 0.1 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Nufarm | Applied | Bulk | No | 99 | -31.3 | 0.1 | 0.2 | 0.4 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Nufarm | Applied | Bulk | No | 99 | -31.5 | 0.3 | -0.2 | 0.2 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Unknown | Applied | Bulk | No | 99 | -29.8 | 0.3 | 3.3 | 0.1 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Unknown | Applied | Bulk | No | 99 | -30.2 | 0.5 | 0.2 | 0.3 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Unknown | Applied | Bulk | No | 99 | -28.2 | 0.1 | -0.2 | 0.2 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| FMC Agro | Applied | Bulk | No | 45 | -30 | 0.5 | 2.5 | 0.1 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| ADAMA | Applied | Bulk | No | 36 | -33.7 | 0.2 | -0.6 | 0.2 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Nufarm | Applied | Bulk | No | 99 | -29.4 | 0.1 | -1.5 | 0.2 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Phytorus | Applied | Bulk | No | 99 | -31.2 | 0.1 | 0.4 | 0.2 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Phytorus | Applied | Bulk | No | 99 | -28.1 | 0.4 | 2.2 | 0.1 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| MONSANTO | Applied | Bulk | No | 99 | -25.8 | 0.1 | 0.3 | 0.2 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| MONSANTO | Applied | Bulk | No | 99 | -24.6 | 0.1 | -0.3 | 0.1 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| MONSANTO | Applied | Bulk | No | 99 | -26.4 | 0.1 | 0.1 | 0.9 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| MONSANTO | Applied | Bulk | No | 99 | -30.2 | 0.1 | 0.3 | 0.9 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| MONSANTO | Applied | Bulk | No | 99 | -30.6 | 0.1 | 0.5 | 0.3 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| MONSANTO | Applied | Bulk | No | 99 | -31.4 | 0.3 | -0.7 | 0.1 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| MONSANTO | Applied | Bulk | No | 99 | -27.2 | 0.1 | -1.5 | 0.2 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| MONSANTO | Applied | Bulk | No | 99 | -27 | 0.2 | -1.3 | 0.3 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Compo | Applied | Bulk | No | 99 | -32 | 0.1 | -0.9 | 0.2 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Compo | Applied | Bulk | No | 99 | -31.8 | 0.1 | -0.5 | 0.1 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Compo | Applied | Bulk | No | 99 | -31.8 | 0.2 | 0.5 | 0.1 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Compo | Applied | Bulk | No | 99 | -31.6 | 0.2 | -1.8 | 0.4 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Compo | Applied | Bulk | No | 99 | -31.9 | 0.2 | -0.3 | 0.6 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Bayer | Applied | Bulk | No | 99 | -25.6 | 0.9 | 1 | 0.6 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Bayer | Applied | Bulk | No | 99 | -25.5 | 0.1 | 0.2 | 0.2 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Bayer | Applied | Bulk | No | 99 | -26.1 | 0.5 | -0.1 | 0.3 | LC-IRMS and GC-IRMS (N) | 10.1007/s00216-015-8721-3 | Mogusu, E.O., et al., Dual element (N-15/N-14, C-13/C-12) isotope analysis of glyphosate and AMPA by derivatization-gas chromatography isotope ratio mass spectrometry (GC/IRMS) combined with LC/IRMS. Analytical and Bioanalytical Chemistry, 2015. 407(18): p. 5249-5260. | ||||||
| Sigma Aldrich | Standard | Bulk | No | 99 | -29.2 | 0.5 | EA-IRMS | 10.1007/s00216-012-6669-0 | Kujawinski D.M., et al, Carbon isotope ratio measurements of glyphosate and AMPA by liquid chromatography coupled to isotope ratio mass spectrometry, Anal Bioanal Chem (2013) 405:2869–2878 | ||||||||
| Sigma Aldrich | Standard | Bulk | No | 99 | -30.4 | 0.4 | EA-IRMS | 10.1002/rcm.9017 | Limon, A.W., M. Moingt and D. Widory, 2021.The carbon stable isotope compositions of glyphosate and aminomethylphosphonic acid (AMPA): Improved analytical sensitivity and first application to environmental water matrices.Rapid Communications in Mass Spectrometry, 35, |